Daily Kos

Our car is on 50% Biodiesel

Sun May 01, 2005 at 05:01:36 AM PDT

Today we went for a typical Sunday drive... stopped off at the sushi bar for a nice lunch. Drove through bumper-to-bumper holiday traffic to a computer shop to buy our son a new hard drive since his self-destructed a couple of days ago, and ended up detouring to a second computer store some distance away. We covered about 50 km. on this drive, and noticed nothing unusual. Nothing strange. Except the exhaust didn't smell so bad like it used to when we first bought the car! And it ran smoother, more quietly. Is that our imagination?

Backtrack to December 2003. The family was wrapping up another glorious Christmas in Hawaii, sitting around a cafe, sipping on some cool drinks when our son began to grill us about possible alternative fuels. Like many kids his age, he's concerned about what kind of environment he is going to have to deal with when he grows up, or what's going to be available to pass on to his own kids. So he wanted to talk about all these ideas... What about water? Can we split it and use the hydrogen? What about solar powered cars? Or electric cars? How can we create some fuel that doesn't pollute, that interacts naturally with the environment? We kept trying to answer his questions, and tried to think of what we had heard about the drawbacks or difficulties of a particular method, and finally I said, "There isn't any alternative fuel we could easily switch to, not the way society is set up now. Somebody has to invent something new that we haven't heard of. If there was something else that we could really use today in place of gasoline, we would have heard of it already."

The reason I remember that particular conversation so clearly is about three days later we were on the flight back to Oahu to catch our homeward flight back to Japan, and my husband was thumbing through the Hawaiian Airlines flight magazine when he came across this article: Clean Getaway. This story described the Maui Bio-Beetle, a rental car that was fueled one hundred percent by recycled vegetable oil. He turned to my son and showed him the article. "There's your alternative fuel," he said.

One of the first things my husband did when he got home was to Google bio-diesel. So it didn't take long for us to realize that there was an alternative fuel which could recycle oil - waste oil that was already part of the carbon cycle - to power cars that were already a part of the existing infrastructure - diesel cars. This is something we could visualize as a transition between fossil fuels and whatever is going to come next - improved public transportation certainly, and possibly those alternative fuels that haven't been invented yet. One of the references my husband found was this book From the Fryer to the Fuel Tank, written by Josh Tickell. We ordered the book, read it, and figured biodiesel was something we'd be able to do when we returned to the West and could have our own garage. So we tabled the idea for awhile.

A few months later I was riding my bike past a small marine engine garage near our house, and I noticed that the business was gone and the garage was up for rent. This building was of a type which would be familiar to anyone who has driven through the American south, a ramshackle structure that was missing a goodly portion of the roof, with dust blowing through the gaps in the walls and bits and pieces of junk still littering the parking area from the previous business. I stopped for awhile and studied this abandoned building, because while I was looking at it, the beginnings of a plan were beginning to form in my mind... Economic times have been hard around here, and this wasn't the only garage that was standing empty. Maybe we would rent this garage - or some other garage. Why wouldn't someone want to rent to us? Well, for one thing - we were foreign. And the idea of brewing biodiesel was bound to sound weird. But we would try to get this garage, and if we couldn't get it, we would keep trying until we got one.

Well, those people didn't rent to us. We were foreign. And biodiesel was bound to sound weird. But that's okay; we got our garage the way just about anything happens in Japan. You get a friend to ask around, and after a while, the pieces come together. In our case, our friend knew an elderly man who was a retired carpenter, willing to rent out a portion of his garage to us. In a way, this was far better than getting our own place. It was invaluable having a carpenter around who - as it turns out - is acutely interested in the project, and always is ready to jump in and lend a helping hand, or help us troubleshoot some practical difficulty or other.

While we were looking for the garage, we were getting ready in other ways. We had to learn more about brewing biodiesel itself; it was going to be more than just collecting waste oil. During our research, we found that several companies had started manufacturing biodiesel stills. Now, we could have scoured junk yards and probably found most everything we needed to build one ourselves, but after much debate, we decided to buy one ready-made. It would be hard enough to be doing something weird in Japan without having the right look. At least if we had some professional-looking machinery, we might just convince people we knew what we were doing.

So the garage was set up - and boy did our new landlord work hard to fix up our cold and drafty and dirty portion of the garage. He found an old kitchen sink with cupboards and put in the piping so that we would have running water. Our friends contributed a kerosene stove, and helped us source an oil heater (in Tokyo). We ordered and set up our biodiesel still and acquired some cannisters for holding waste oil and our final product biodiesel. We found out about buying lye and methanol (both controlled substances here), and started sourcing waste oil. One afternoon my son and his Japanese teacher rode around on bikes visiting different fast food and obento (boxed lunch) shops. He learned that donut shops don't have good waste oil, that hamburger chains aren't allowed to give away their waste oil - but that the local obento shop was happy to donate! A good afternoon's Japanese lesson.

So we had our oil, our lye, our methanol. We had our biodiesel still set up in a garage that seemed to average about 5 degrees centigrade on a winter's day (it seems summer is the ideal time for brewing biodiesel). But we still had a lot to learn. One of the first things we learned that if water gets in your waste oil, you're screwed. This has been about the rainiest winter since we moved down here to Nagasaki, and - unfortunately - at least one of our waste oil donations was contaminated with water. Quite a bit of water. So we learned all about heating oil and drying oil and pumping out water that has fallen to the bottom of your tank, and then doing the whole thing again about five times, until finally you have a decent sample of oil and can produce a good mini-batch.

It wasn't real easy getting this far, but it was never exactly hard either. It isn't the same as going to your local gas station and filling up the tank, but it's a nice family project to work on together (we send our son out of the garage when we're adding the lye to the methanol!), with the further benefit that we've been able to show our son some important things that we wanted him to know: first, that we are doers, not just talkers (or, complainers, if you will), and that if major corporations set up a virtual monopoly on the way things have to be, you still don't have to support their monopoly. You might just have to look for a creative way around it. I hope he will remember these days with us, and he will remember these things we have tried to teach him.

I have developed a system at home for filtering biodiesel before we add it to the tank ( a final precaution to make sure no food particles survived the previous filtering and washing stages), which involves pumping it through a coffee filter into four-liter pickled plum jars. Today we added enough of this filtered biodiesel to our Nissan Terrano* to bring us up to 50% - the current stage on our way to 100%. My husband took the car for a little spin around the neighborhood, and as he drove off, I thought to myself, "Didn't that car used to stink real bad? Now there is just a faint whiff of dino-diesel in the air, along with something else..."

*In the U.S., this would be a Pathfinder, but in Japan, these are available in diesel. We purchased this car secondhand when we started looking to replace the gas-powered Toyota my husband uses for work.

Tags: (all tags) :: Previous Tag Versions

Permalink | 55 comments

  •  Some details (4.00 / 10)

    The waste oil, which we get for free, needs to be reacted with methoxide (lye and methanol) to create biodiesel and glycerin.  The glycerin might be anywhere from 5 to 20% of the product, but we have been averaging around 12 to 15%.

    The methanol costs us about $1 a  liter and together with the NaOH brings it up to about $1.20 for a liter of methoxide catalyst. 1 liter of methoxide makes  about 5 Liters of biodiesel after cracking off the glycerin, which  makes our current biodiesel about $0.30 a Liter vs. $1.20 a liter for regular gas (we have to multiply by 3.87 to convert liters to gallons, but if we round up to 4, it comes to around $4.80 a gallon for gas in Japan).

    •  Watch out for too much success (none / 1)

      The waste oil, which we get for free

      As more people adopt this technology, the waste oil will no longer be free but will depend on supply and demand.  If people start eating healthier a lot of the sources of this waste oil will disappear.  But farmers who grow vegetable oil crops with have a greater market.

      Not to criticize;  I think this is a great idea.  Just to remember that popularity has killed a lot of good ideas--for example, a Florida vacation.

      Alternative fuels need to be a polytechnology instead of a monotechnology.  This spreads the risk of shortages over several technologies instead of having to depend on a single one like fossil fuels.

      •  I'm glad you mentioned this. (4.00 / 2)

        I agree, but I think that mainstreaming something like this into our infrastructure has its advantages too. It will be a lot easier for people if they could just buy it and put it in their cars, rather than if they had to source the waste oil and brew it themselves.

        As for running out of waste oil, surely that would happen at some point. But people are already looking for alternatives to waste oil. Third and fourth pressings - producing low quality oil - might be one way. Here is an interesting one from the University of New Hampshire: Widescale Biodiesel Production from Algae. In this case, the algae could feed on human waste, so you would have a way to get rid of that sort of waste, while producing algae oil that could be converted to biodiesel.

        •  Mainstreaming... (none / 0)

          Mainstreaming has started to happen, just a little. I actually saw BioDiesel at the pumps in San Diego when I was out there about a year ago. Haven't seen it anywhere else yet. Don't know what exactly they're making that out of and it was still more expensive than regular diesel, proabably due to it being a smaller market and to some extent the customers are paying for setting up the initial infrastructure.

          I'm just sad that CA won't allow the sale of TDI cars yet so I had to get the gasoline version of the PAssat, even though a TDI version is sold in other states.

          conscietious objector in the battle of the sexes

          by plymouth on Sun May 01, 2005 at 09:17:35 AM PDT

          [ Parent ]

        •  The guy who wrote this... (none / 0)

          Hangs out at (and is the administrator of) www.biodieselnow.com.  There are a lot of developments in this area which would be quite interesting, but right now the people who know the most aren't saying much - there are intellectual property and patent issues involved, and until they get all of that paperwork done, they are going to have to keep quiet.
      •  Also, we can't forget about conservation. (none / 0)

        Also, alternative transportation which you mentioned in the diary.

        Congratulations on actually doing instead of talking, and for teaching your son, as well as all of us. Good stuff!

      •  Don't let the fear of success--- (none / 0)

        ---- stand in the way of your success.

        Looking for Good Reason

        by Clzwld on Sun May 01, 2005 at 08:09:37 AM PDT

        [ Parent ]

        •  Exactly right (none / 0)

          Which is why we have to have a vision of how mainstreaming will unfold.

          Otherwise, we're like those folks at GM who are "building a hydrogen fuel cell car".  Only they haven't thought through where the hydrogen is coming from or how you get it to where the cars are.  Or how you transport it safely and pump it safely.  Not   that hydrogen fuel-celled powered car would not be a solution.  It is obvious that GM and the other carmakers are just stalling having to meet fuel efficiency standards.

  •  wow! it sounds like an amazing project! (4.00 / 5)

    i wish regular vehicles came in diesel in the us.  how much would you say investment in the equipment do you have?  and they have had stories about people in us running on used oil... and they just take it straight from the drums outside the shops to their vehicle.  apparently here restaurants have to pay to have the waste oil removed!  sometimes more than the oil cost in the first place!!  

    i think biodiesel is where we are headed.  not that the administration is doing anything to help it along.  eventually i think the cost of gas will force someone to do soemthing!

    i keep thinking of all the farmers going under.  imagine if we had a renewable way to fuel our cars without destroying our environment.  and give farmers something to grow that they could make a living off of!  Instead of paying them not to grow crops.

    <sigh>  Sometimes it seems like people will never wake up and do just what you are doing.  i wish we had the means to take on a project like yours.  even if it was just to run our lawn tractor!  someday.

    •  It is an interesting project. (4.00 / 2)

      You are right about the paucity of good diesels in the U.S. There are a lot of ways that getting started here is more difficult than the U.S. - for instance, we needed to rent a separate garage... But the easy access to quality secondhand diesel cars has been one of the benefits about getting into bio here.

      As for the cost of equipment... We have to pay for renting the garage, but actually I don't mind that because it's nice to have a place where we can do projects, not just this one but other things too. And our biodiesel still cost a couple of thousand dollars, but it isn't necessary to spend that much. There is a lot of information now about building these stills from junk; here is a site, for example, with a lot of information on this subject: Journey to Forever. Also, Biodiesel & SVO Discussion Forums is a veritable gold mine for people interested in biodiesel.

      We felt it was necessary to have a good presentation here in Japan, so we didn't mind spending the extra to have something that looked professional. In essence, I think it's a project that could be done very cheaply by people in the right situation, or more expensively by people like us in a trickier situation... Or it would be very hard for some people to do at all, so it would be nice for people to be able to join biodiesel collectives or have other means to pay for it.

      You are right, doesn't it make more sense to run a lawn tractor on waste oil than digging fossil fuels out of the ground in Alaska?

    •  Volkswagen (none / 0)

      I have been driving a diesel Jetta since 99.  The engine is great!  Quiet and quick.  My MPG is in the 40's.  I have been watching the biodiesel availability for sometime.  Still not available where I live in PA but there is a place in Delaware.  Unfortunately not close enough for a standard fix.  

      "You have attributed conditions to villainy that simply result from stupidity"

      by newfie on Sun May 01, 2005 at 07:06:20 AM PDT

      [ Parent ]

      •  if there could be someway to be able to use (none / 0)

        diesel and the biodiesel.  that way you could use regular diesel when the other isn't available.  like say you wer going to take a long trip.
        •  That's not a problem. (none / 1)

          Biodiesel is a drop-in replacement for regular petroleum diesel in most circumstances.  I understand that some older engines have trouble with biodiesel (it can attack some of the rubber components people used to use), but if your engine can run on biodiesel, it can run on petroleum diesel as well.
          •  thanks. that is intriguing. (none / 0)

            i think i am going to start doing research into this more carefully.  though checking on one of the boards suggested, i am nervous in regards to the epa and stuff.  thanks for al the info.  its a truly fascinating possibility that should be discussed more.  i know my bf was talking awhile back about investing in some biodiesel company.  
      •  Check the above links for away to do your own! (none / 1)

        Just a red meat eating Democratic dawg...frontpaging at The Democratic Daily

        by BigDog04 on Sun May 01, 2005 at 08:38:26 AM PDT

        [ Parent ]

        •  hmmm... (none / 0)

          Thanks.  Now I just have to get my wife to buy into that.  She did acquiesce on the beer but I'm not so sure that she will on biodiesel.  Oh well, nothing ventured nothing gained ;o)

          "You have attributed conditions to villainy that simply result from stupidity"

          by newfie on Sun May 01, 2005 at 05:17:58 PM PDT

          [ Parent ]

    •  more likely use as a fleet additive (none / 1)

      I've been researching this topic for about a year now.  And while it would certainly be nice to use in our cars, we don't have many diesel cars in the US.  But we do have LOTS of diesel trucks.

      Starting in about 1999, large state and municipal fleets (which under EPAct are required to earn "alternative energy" credits) were given incentives to use biodiesel in their machinery.  It tuned out to be the most effective way to satisfy EPAct requirements, since most fleet machinery already runs on diesel.

      It also turned out that many of these fleets had pretty good experiences with the stuff.  Keene New Hampshire converted their entire city fleet.  Even their emergency vehicles.  Berkeley California is another example.  Biodiesel trials went so well in frigid Minnesota that starting next year, ALL diesel sold there will have to be blended with at least 2% biodiesel.

      And I can't say that the Bush admin has done nothing on this matter.  In January, a tax incentive was given to distributors of biodiesel, which brought it to price parity with petroleum diesel here in the Northeast.

      Now 40 million+ gallons of biodiesel are sold every year.  That's last year's figure actually and it has been close to doubling every year.  But we also consume more than 60 billion gallons of diesel every year.  Our current biodiesel production is a "drop in the bucket."   Also, the preferred method of manufacture for it in the US is from virgin soybeans, not waste oil.  We are in a bad place for replacing all our diesel demands with biodiesel unless, for instance, algae becomes viable.

      But we are on track to follow Minnesota's lead and, if it were seen as necessary, we could mandate biodiesel use as an additive.  This has many benefits by itself, and in combination with the implementation of Ultra Low Sulfur Diesel (brought to you by the Clinton folks) next summer.  They include cleaner, smoother, quieter running, and extended service intervals in addition to a partial replacement of petroleum demand.

      "listen all y'all this is SABOTAGE" - beastie boys 1994

      by mr northstar on Sun May 01, 2005 at 08:16:41 AM PDT

      [ Parent ]

    •  most VW models have diesel version (none / 0)

      VW Jetta, Golf, Beetle, Passat...what's not "regular" about these?
  •  garbage trucks (none / 0)

    Your diary is one of the most interesting I've read on dKos.  I love all the personal details, and the important subject.  BTW, I've heard there are garbage trucks in Berkeley, CA that run on biodiesel. It's said they emit the smell of french fries.  True?
    •  I have heard about that French Fry smell too! (none / 1)

      Last year, my son and I had a free day in Berkeley when we were visiting the U.S., so we took the opportunity to travel out to the Ecology Center, where members of the Berkeley Biodiesel Collective meet. Our free day did not coicide with any meetings of the BBC, but my son did purchase a "The Emperor has no Brain" pin to wear in advance of the November election... and we did learn more about the city of Berkeley's biodiesel program. They said that they planned to have every diesel vehicle owned by the city running on biodiesel.

      We thought that was a terrific idea. Unfortunately, when I was just getting the link for the Ecology Center, this headline caught my eye: Spare Berkeley's Pioneering Biodiesel Program from the Budget Axe. It sounds like this program is in trouble. I hope interested people in the Berkeley area can make a difference and save it.

  •  I've been lookint at this for some time (none / 0)

    The question that has never been answered for me is how much time does it take to produce enough bio-diesel to run a car for a couple of days.  I have an excellent source for older diesel Mercedez Benz cars with an excellent mechanic that goes with. Once I'm in upstate NY, I can get going but I'm a afraid to take this on without an ongoing nversation with people who have done it. Have you considered a blog specifically about the topic or do you know of one that already exists? I'm not particularly interested in a general alternative energy blog.  I know they are around.  I would be very interested in a blog specifically about bio-diesel.  I know that another couple have moved to Troy who may be interested in doing this cooperatively.

    By the way, are you using the glyercin to make your own soap? I remember my mother using a similar technique to convert animal fat to soap during the Korean War.

    •  Go to www.biodieselnow.com... (none / 0)

      and all questions such as this can be answered.
    •  Diesel Mercedes (none / 0)

      It sounds like your Mercedes project has some good potential. Someone forwarded this article to me a couple of months ago: The Mercedes Wrangler is riding the eco-range, and I recommend you read it, since it is about someone doing the same thing in California.

      Also, Biodiesel and SVO Forums has a comprehensive section on Mercedes, so go there and have a look while you are thinking about it. This forum isn't the same as a blog, but it is really an excellent place to ask questions and learn from other people's experiences.

      We haven't gotten around to learning about soap-making yet, primarily because before you can use the glycerin by-product for soap, you have to be sure that you have gotten rid of any excess methanol. I think it can be done, but personally I'd prefer to find someone else and pass it off to them. There are people who use waste glycerin here, so it's a matter of being patient and finding the contacts.

  •  Wow... (none / 1)

    I had no idea husbands were so cool!

    -9.0, -8.3. History is more or less bunk.--Henry Ford
    Henry Ford is more or less bunk.--history

    by SensibleShoes on Sun May 01, 2005 at 07:03:25 AM PDT

  •  Diesel veg. oil conv. kits (4.00 / 3)

    Hi,

    Hope this doesn't ruin all the effort you put into your project!  :)  Though, it sounds like it was a great family project...

    http://www.dieselveg.com/conversion%20info.htm

    Just one of several that sells veg. oil conversion kits where you can fill-er up directly with used & strained veg oil.

    --Bush lied, thousands died

    by indyjones48 on Sun May 01, 2005 at 07:11:19 AM PDT

    •  Have you also been considering (none / 0)

      converting?  The information is helpful.  Wonder if I can buy that particular conversion kit here in the US.  It looks like it's about 2000 US, which isn't a bad deal of its put on a car that holds up well
      •  Looked into it... (none / 0)

        To see if it was comparible to buying a Hybrid.  If I remember right, you'd have to ship a kit from Europe, but even with that additional expense, it was only a little more than a Prius (assuming you purchased a new VW Golf TDi, etc.)

        --Bush lied, thousands died

        by indyjones48 on Sun May 01, 2005 at 04:40:32 PM PDT

        [ Parent ]

    •  OK in hot places, but (none / 0)

      straight oil use may require a preheat if you live in areas where it drops too low in temp at night.
      •  The conversion kit covers that... (none / 0)

        as well, AFAIK.  Bsically, the heat from your engine warms the oil.  At start-up and power-down, you have to use reg. diesel to get the oil warm, and then remove any leftovers from the engine...  The kits I've looked at require a second, small tank to hold the diesel.

        --Bush lied, thousands died

        by indyjones48 on Sun May 01, 2005 at 04:37:51 PM PDT

        [ Parent ]

    •  Vegetable oil conversion (none / 0)

      You are absolutely right - anyone who wants to get into using waste veggie oil as fuel has two alternatives right from the beginning. Either you convert the car to handle straight veggie oil, or you convert the waste oil so that it can be handled by a regular diesel engine.

      For us there wasn't ever any consideration of the first option. Japan has strict auto inspections and trying to get a car that we had adapted ourselves past one of those inspections.... Well, let's put it this way, the Japanese have many good qualities, but flexibility in bureaucracy just isn't one of them.

      No, for us it had to be converting to bio-diesel or nothing... but that doesn't mean it has to be that way for everyone. Personally, I prefer to see as many options as possible. A range of options would certainly start with good public infrastructure, including widely available public transportation and good bike lanes; SVO for some vehicles and biodiesel for some others, esp. heavy machinery, diesel trains, and trucks; hybrid cars (more and more people are driving the Prius here, and you can really tell the difference when you are behind one!), and more. In the long term it would be nice for people to be able to walk somewhere for quick errands like mailing a letter or picking up a loaf of bread too. Where my parents live, every single errand involves a car trip.

  •  Yay! (none / 1)

    What a great project.  You sound like wonderful parents.  I hope my kids are this curious and involved when they are older.

    I have a low tech question for you.  My sister-in-law owns an early 1980s diesel Mercedes stationwagon.  She parks it in the same place in the driveway every day and I noticed that the bushes next to her exhaust pipe are all brown and dying. Is this due to the diesel being "non-bio"?  Would bio-diesel do the same thing?  Is the availability rather than the non-polluting aspects of bio-diesel what makes it appealing?

    NetrootNews coming soon!

    by ksh01 on Sun May 01, 2005 at 07:32:32 AM PDT

    •  Lower pollution (4.00 / 2)

      Certain components of Bio-Diesel exhaust are lower than regular diesel.  I can't remember off the top of my head.  Either exhaust still has quantities of CO, CO2 (which plants use), NOx, HC, and particulats.

      Ok, so I looked it up.  HC is slighly lower.  the CO2 is of no concern - it was already pulled out of the atmosphere for the plant's photosynthesis.  So effective CO2 production is ZERO.  In fact, one point on the page said that growning soybeans consumes 4 times the CO2 as that given off when burning it as bio-diesel. The article I read also says emmisions that lead to smog are lower.  But, I can't remember which of these do that.
      Many diesels from the '80s, Mercedes included, are known for emmitting a lot of particulats (solid black soot that can been seen)   Trucks in the US are still horrible at this.  Modern cars are very good at limiting the particulats.  Also, any exhaust out of a vehicle's tail pipe is extremely hot.  I don't think your plants are going to appreciate that one bit.

      •  NOx slightly higher with biodiesel (none / 1)

        ...but that's probably not a huge long term problem.  NOx can be removed with the diesel equivalent of catalytic converters, which should become more common when low-sulfur diesel fuel becomes normal.  

        A minor nit:  Net CO2 emissions are a lot lower than for petroleum diesel, but not quite zero, because of the methanol used to make the biodiesel.  That still usually comes from fossil fuels of some sort.  If you used ethanol (from plants) instead, you could get net CO2 pretty damn close to zero, but the reaction is trickier.

      •  Biodiesel emissions and references (none / 1)

        Switching from petro-diesel to biodiesel for heavy duty trucks and buses provides some tailpipe emission and greenhouse gas benefits, but when considering getting rid of your gasoline car to buy a diesel car, tradeoffs become far more complicated and multifaceted.  The higher nitrogen oxide (NOx, an ingredient in urban smog) and particulate matter (PM) emissions of a biodiesel car are counterweighed by other benefits, such as lower hydrocarbon (HC) emissions, lower sulfur emissions, biodiesel's renewable nature, lower CO2 emissions, better fuel economy, and excellent durability of the engine.  Note that because biodiesel is derived from plants, the total life cycle emissions of CO2 are probably far lower than for gasoline.

        The table below shows emissions on a grams per mile basis for the 2003 Jetta wagon.  In each case, the diesel car has much higher emissions of smog-forming chemicals, and consequently receives a lower emission rating from the EPA.  On an emission per mile basis, switching from a gasoline car to a diesel car leads to a NOx increase of between 5 and 10 times, and a hydrocarbon (HC) emissions decrease of 5 times.  Particulate matter (PM) emissions increase significantly because gasoline cars have almost zero PM.  Replacing the petroleum diesel with biodiesel would reduce the particulate and hydrocarbon emissions by roughly 50%, but have little effect on NOx emissions (and the particulate emissions of a biodiesel car are still higher than those of a gasoline car).  Note that unless emission regulations are relaxed, diesel cars in 2008 and beyond will have almost undetectable particulate emissions (0.01 g/mi) and the same NOx emissions as gasoline cars, and a biodiesel car will likely be superior to a gasoline car in almost every way.


        Emissions of 2003 Jetta Wagon on certification cycle, g/mi

        Engine          NOx        Hydrocarbon   Carbon   Particulate
                                              Monoxide    Matter
        Gasoline   0.06 - 0.11       0.1      0.4-1.5     ~zero
        Diesel      0.5 - 0.7        0.02       0.2       0.05

            Source:  EPA.  See also EPA Green Vehicle Guide

        When thinking of the long term, however, life cycle analysis is important.  One of the best scholarly studies of the biodiesel life cycle is this one:  
        Life Cycle Inventory of Biodiesel and Petroleum Diesel for Use in an Urban Bus

        Other good technical sites are NREL's Alternative Fuels Data Center and U.S. Department of Energy biofuels program and EPA's emission rankings for cars and light trucks.  

        •  NOx and Biodiesel (none / 1)

          Here's hoping people are still reading this diary...

          Anyway, biodiesel use does not necessarily mean elevated NOx levels.  In constant-flame machinery like home heating furnaces, there is even a reduction in NOx emissions over petroleum diesel.  The issue is injection timing in CI (compression ignition) engines.  Injection timing that is appropriate for petroleum diesel is too advanced (too soon) for biodiesel.  

          The solution is to retard timing by a couple of degress.  NOx emissions are reduced to baseline diesel or perhaps reduced, and some of the (small) power loss from biodiesel is mitigated as well.

          There's no reason that newer diesel engines can't have engine controls that are sophisticated enough to do this automatically -- and perhaps some do.

          There are also additives that are called "fuel-borne catalysts."  They include small amounts of the heavy metals found in catalysts and  are claimed to help reduce NOx emissions as well as completing combustion.  I can't speak to their effectiveness.

          "listen all y'all this is SABOTAGE" - beastie boys 1994

          by mr northstar on Sun May 01, 2005 at 11:55:53 AM PDT

          [ Parent ]

  •  This Subject is so interesting to me (none / 0)

    Thank you so much for the post. I have been sitting on the edge of this pool for a year.
  •  Here's a couple of US versions! (none / 1)

    a fully working still with filter from eBay...expired auction but the company keeps one up all the time:
    http://snipurl.com/eld0

    And one of the complete US bio-diesel sites that runs down the entire sujbect (there are many):
    http://www.biodieselnow.com/

    When I get my next vehicle I'll get it outside of CA and make sure it's a diesel. Right now the only viable new diesel auto in the US is a few of the VW line.

    Since I haul/train horses in my off hours, and intend to make that my real busines in the future, I'll get an older diesel and convert it. Contrary to most thoughts...the conversion is a snap too. There are a few models that don't take well too it. But all the modern VW's do. Too bad CA can get it that the modern Diesel car, which is common in Europe is a good thing!

    A Google search turned up 14,400 references.

    As someone interested in the topic for sometime I want to warn the newbie to the idea of one thing to watch for as you read the articles:
    You will continually read that the current supply of either 100% bio-diesel or B-20 isn't cost effective compared to regular diesel!
     *A. This is before the last run up in Diesel prices
     *B  This assumes you go to the FEW ACTUAL BIO_DIESEL stations and buy it from the pump instead of refining your own.

    It's a facination topic.

    There is also fascintating stuff at another blog, fully sourced with data references on the reality of Hydrogen research. And the currene meme that Hyrodgen isn't energy effecient is wrong if these technologies are used. Very frustrating article to read. Worth the effort.
    http://earthfamilyalpha.blogspot.com/2005/04/heliohydrogen.html

    Also if you haven't taken up the banner of the The Apollo Alliance you should look at it as it's dedicated to finding a proving new energy resources we haven't even thought about yet.

    Just a red meat eating Democratic dawg...frontpaging at The Democratic Daily

    by BigDog04 on Sun May 01, 2005 at 08:37:24 AM PDT

  •  thanks for the post (none / 0)

    You inspire me to start my own factory, which I have been thinking about.

    Here's a question for you : do you feel it's safe to make this stuff?  My wife is not keen on it - she says I'm too prone to spill things.  But barring spills - it's pretty darn safe - don't you think?  Be careful with the methanol and lye and you should be fine, I'm assuming.  I believe I use more harmful substances at work in R&D at a biotech (mutagens for instance).

    Second, does anyone have an idea about the legality of using home-brewed diesel in their cars in the US?  Not like it would be a high priority for law enforcement or that I'm concerned about it - just curious.

    If you're lucky enough to live in the Seattle area, there are several places to purchase bio-diesel already, with more on the way.

    Here is an excellent article on the newest biodiesel producer in Seattle: http://seattlepi.nwsource.com/local/212618_biodiesel18.html .  They've even reclaimed a couple of huge drums from the old Rainier Brewery.  I don't know if they're actually opened yet.

    It's an informative article from the Seattle PI and details how local buses and ferries are already using fractions of biodiesel for power.

    A Man Without A Country - Kurt Vonnegut

    by tedward on Sun May 01, 2005 at 08:56:37 AM PDT

    •  Keep in mind... (none / 0)


      that you are handling chemicals.  Lye is nasty if you spill it.  Methanol is a fire/explosion hazard if the vapors collect in an enclosed area.  Thus you really want either a well ventilated area, or you want advanced methanol recovery systems.

      My understanding is that people who home-brew don't pay taxes.  I don't know if this is because they are exempt, or if this is because it is such a small number of people that it isn't worth it for them to go after you.

      I purchase all of mine at retail pumps, so I do pay the road tax.

    •  Safety concerns (none / 0)

      Tedward, if you decide to make your own biodiesel, you can do it safely, but as the poster above mentioned, when you are handling lye and methanol, you never take any chances.  Always go by the book.  You need to have safety gear - eyewear and dust masks and gloves and aprons - when you are dealing with these chemicals.  And methanol is explosive, no open flames around it.  In general, you don't want to get this stuff on your skin or to inhale it or get it anywhere near your eyes.

      We run some of our tests (titrations and mini-batches) in our kitchen.  So I set up a completely clean area, run the tests, and make sure everything is completely cleaned up again before I go back to using the kitchen for cooking.  

      We do some titrations and measuring of lye and pumping of methanol in our garage.  We have everything set up and are ready to handle spills (which are inevitable, of course). Methanol should always be handled in a closed system with no smokers in the vicinity.

      (Someone may have mentioned this in one of the posts already, but ethanol can also be used instead of Methanol.  It is much kinder to the environment, but it is a little more difficult to get the reaction right.  That is because you have to be 100% sure that your ethanol is %100 percent free of water.  I think that is something we will work on when we are back in an English speaking environment.)

      ANyway, back to safety....if you take these  concerns seriously and never ever deviate from them, you should be able to make biodiesel safely.  The methoxide reaction takes up only a small part of the whole process of making biodiesel, but it is essential.  

      For us, the biggest part of the process is gathering waste oil and filtering it.  We are still working on ways to get the filtering time down.  Filtering and keeping water out of your waste oil are the keys to making good biodiesel.

      As for the legality of biodiesel, it is probably difficult to speak for fifty different states and federal regulations, but I remember reading something about how the feds will let you brew up to 400 gallons per year for home use before they ask you to start paying taxes on it.  Personally I don't have any problems with paying fair taxes, as I would be using the roads and attendent services, but what I would object to is a punative tax placed on biodiesel brewers at the request of Big Oil.  I believe Big Oil gets enough support with our government dollars already.  

      A related issue I have heard of is regulating the kind of oil used by people who want to make biodiesel. I have heard there are some attempts to make soy oil the standard.  This just seems plain wrong to me - it is an attempt to constrain the potential market and benefits to enhance the profits of a certain group.

       

      •  Soy biodiesel... (none / 0)


        I must admit that while the commercial biodiesel I purchase is made from soy oil, I am not aware of any attempt to make this the only form of acceptable biodiesel.  It would be quite counterproductive.

        For several reasons soy oil isn't ideal.  It just happens that we have lots of it that is left over from making chicken feed, so we might as well use it.

        The problems with soy biodiesel are twofold.  First the cold-weather properties aren't as good as biodiesel made from other forms of oil.  Secondly the yield of oil per acre isn't as high as with other crops.

        In Europe, they use rapeseed oil - something quite similar to canola.  The yields are higher and the cold weather properties are better (you can take it to lower temperatures before it starts to gel up on you).

      •  absolutely, yes, (none / 0)

        I'd take the precautions that you recommend.

        I have taken college organic chemistry so it's probably about the same level of care you must take  Plus, occasionally at work I have to get out the chemicals and mix up a batch of something or other.  But thanks for the information.  My wife's main objection is that I'm always spilling something ;).  

        I did just order the book "from the frying pan" something something.  Looks like a good one.

        As far as legality is concerned, my question was less about taxes (which I'm also fine with) and more about safety and environmental regulations.  Just because it's said to be cleaner by some folks on the web doesn't make it so!  Although, I'm inclined to believe that you've done your homework.  But I'll put in my due diligence as well.  Thanks!

        A Man Without A Country - Kurt Vonnegut

        by tedward on Mon May 02, 2005 at 07:52:47 PM PDT

        [ Parent ]

  •  Could biodiesel be banned? (none / 0)

    I had to peel off this discussion to read off-line, but am very interested. There is some bio-diesel production in my area, a course at local college (Central Carolina Community College) and a soy-farmers bio-diesel collective that recently advertised in mag of my local electrical co-op, all this in N. Carolina.

    Long story short I got round to checking fine print of the energy bill "Draft" for other reasons (actually nuclear) and found a section on "Boutique Fuels"--a term I'd never heard, which sounded like something right out of the GOP Frank Lutz playbook. Don't call them bio or conservation, make em sound like something from Hollywood.

    Anyhow the entire Energy bill is so bad and outrageous that it needs not be fixed (remove drilling, add renewables sort of funding) but rejected entirely.

    Meanwhile check out wording by going to Library of Congress "Thomas" (as in Jefferson) site. Searches aren't saved, so you will have to type in bill number: HR  1640, and click on "bill number" then search. Then scroll down through list of sections in bill to "boutique fuels"

    start here

    Maybe someone who is more involved in the production and distribution of bio-fuels can tell whether or not this or other possible sections of the energy bill could prevent wider development or use of this fabulous fuel source that cuts into Big Oil's profits.

    •  Boutique fuels refers to something else... (none / 0)


      What was happening is that each state has it's own regulations regarding additives and whatnot, and this makes it a nightmare for refinieries.  This can lead to spot shortages in some states and not others.

      While there is a lot in this bill that I think really stinks, I don't have a problem with this specific part of it.

  •  a little OT but a humorous article on biodiesel (none / 1)

    http://www.greaseworks.org/print.php?sid=219

    I had a question above regarding the legality of home brewed biodiesel : in short the answer is up in the air.

    Funny article, though.  I'd heard of Willie Nelson's support of biodiesel - in fact there's a "BioWillie" product -B20- that's sold at truck stops.  And Neil Young's tourbuses run on biodiesel - as does Jonathan Richman's 1980s Mercedes.  Cool.

    A Man Without A Country - Kurt Vonnegut

    by tedward on Sun May 01, 2005 at 09:18:39 AM PDT

  •  I have been using biodiesel for almost a year now. (4.00 / 2)

    Where I am, I can purchase the fuel commercially. I started with blends like B20, and after a while I got comfortable with that and went whole hog to B100 (100% biodiesel).

    The steps required were first to purchase a diesel vehicle (in the U.S. Volkswagen TDI seems to be preferred - models with a stick can get nearly 50mpg).  The second step is to pull up to a retail pump and fill up.  That is just about all there is to it*.

    No messing with chemicals or waste oil.  Just like fueling any other car.

    *Note: in the winter you may have to blend BD with Kerosene to prevent fuel gelling.  Depends upon the temperatures in your area.

    •  Cold weather... (none / 0)

      One thing I forgot to mention.  Where I live, the "B100" that I purchase is winterized for us by the place we buy it from.  They add the requisite amount of kerosene to keep it from gelling up on us, so it is all the easier.  The problem is that they don't do a good job of informing people that they do this (they don't put a sign on the pump), but if you ask they will tell you.  Not every BD vendor adds the kero to winterize, so you should be in the habit of asking if you are unsure.

      The term "cold weather" depends a bit on what type of oil was used to make the biodiesel.  For biodiesel made from soy oil (common in the U.S.), when the temperatures below about 35F you need to start to think about it a bit.

      We are at now a time of year where this stuff doesn't matter, but I would recommend that folks new to biodiesel take the trouble to hang around the forums at www.biodieselnow.com (and tdiclub.com if you are a VW driver) to learn what the issues are, and how to avoid problems.

  •  There is confusion in the press... (none / 1)

    about what exactly biodiesel is.  People hear these stories about cars that fill up behind restaurants, and assume that this is biodiesel.  If you do this to an unmodified diesel car, you can really screw it up.

    You have two choices.  The first is to modify the vehicle - for this you would want a greasecar conversion.  Runs about 1000$ as I recall.  If you do this, then you can go to the restaurant, and fill up with used fry oil.

    The other is to modify the fuel itself.  The process involves alcohol and lye, as described above, and this turns the vegetable oil into something that can directly be used in a diesel engine without modification to the car.  Fuel that you purchase commercially at a biodiesel filling station will fall into this category.  Chemically this type of fuel will be known as a methl ester.  Sometimes alkyl ester (more generic term for the same thing).

    There are pros and cons to each approach.  It is unclear as to how well engines tolerate straight vegetable oil in the long run.  Generally engine manufacturers will only warrant the use of methyl esters.  If you go the greasecar route, you are on your own.

    •  on the conversion (none / 0)

      you really can use oil straight from the fryer?  do you need to get the water out?  and, I assume, you ought to strain it at least?
      thanks, i'm really looking forward to doing this myself!

      A Man Without A Country - Kurt Vonnegut

      by tedward on Mon May 02, 2005 at 07:56:12 PM PDT

      [ Parent ]

  •  One last point - my beef about CARB states... (none / 1)

    The long term plan is to have diesels be just as clean as normal gasoline cars.  In order to accomplish this a couple of things need to happen, and the next important milepost is in Jun 2006, when the nation's diesel fuel starts switching over to ULSD - ultra-low sulphur diesel, which can have no more than 15 ppm of sulphur (down from 500ppm).

    There are a couple of advantages to getting rid of the sulphur.  For one, the sulphur comes out the tailpipe as sulphur dioxide, and nothing good can come of that.  Secondly, the presence of the sulphur in the exhaust would destroy any type of catalytic converter that is placed in the exhaust system to reduce NOx.

    The second piece of this is that a PM filter (particulate matter - in other words soot) will need to be added to reduce the soot.  Current cars are much better than they were 20 years ago, and for that matter, reducing the sulphur will automatically cause a further reduction in soot, but further improvements are needed to meet the new standards.

    So far, so good.  Everybody wants cleaner air, right.  Well, California jumped the gun.  They said they wanted diesels to meet the new standards as gasoline cars now.  The problem is that the new ULSD hasn't been rolled out yet, so the car manufacturers aren't supplying vehicles that meet the new standards.  This leads to a weird situation where you cannot purchase a new VW diesel car that gets 45-50 mpg, but you can still go out and get a Hummer that gets 10mpg.  Like that makes any sense.

    Folks in CARB states end up having to purchase used diesel vehicles from non-CARB states.  I think the rule is that it has to have 7500 miles on the odometer, and then you can bring it in and register it.  Something along those lines.

    I should add that biodiesel itself has no sulphur in it, and when you use biodiesel, the amount of soot is considerably reduced from what you would get if you were using straight old #2 diesel.

  •  Makes sense... n/t (none / 0)

    --Bush lied, thousands died

    by indyjones48 on Sun May 01, 2005 at 04:34:44 PM PDT

Permalink | 55 comments